MATERIALS AND EMISSIONS
Fume filtration units and VOC's.
Lasers are an essential tool in industry for cutting, marking and engraving a vast range of materials (plastics, paper, wood and more).
In virtually all the above operations, some form of fume is given off as the laser thermally decomposes the substrate to a greater or lesser degree. This fume is a mixture of particulate and gaseous matter.
Fumes from materials such as glass are mainly particulate, the majority of which is less than 1µ (micron) in diameter. Organic materials, particularly plastics, produce much more complex fumes.
Most particles are spherical and roughly 90% by weight are less than 1µ in diameter. These particles fall within the respirable range and need to be removed from the working environment to prevent bronchal or lung damage. The gaseous organic compounds produced are known as Volatile Organic Compounds, VOC's.
The VOC's produced are a mixture of the following:
- Aliphatic hydrocarbons: alkane, alkene
- Aromatic hydrocarbons: benzene, toluene, xylene
- Aldehyde: formaldehyde
- Polycyclic aromatic hydrocarbons: benzo(a)pyrene
- Some materials have other specific groups e.g. PVC polymers generate HCl, 2 component epoxy polymers yield amines and PET generates THF.
A considerable number of the above have occupational exposure limits set for them. Obviously, as with the particulate element these gases need removing from the workplace.
Materials and Emissions
CO2 lasers are commonly used to code, mark, engrave, weld or cut components or products which are manufactured from a variety of materials. Hazardous fumes and dust are produced when the substrate, lacquer, paint or coating is marked or cut. CTR filter systems not only ensure compliance with International Health and Safety Law but also deliver actual cost savings to the production process.
Please see the below tables for details on materials, emissions and possible health issues.
| Emissions Produced During Laser Processing of Non-Metals | ||
|---|---|---|
| Material | Emissions | Other Emissions |
| Kevlar | Respirable dust | Benzene, HCN, No2, PAHs |
| Polycarbonate (PC) | Respirable dust, Cresol | Phenol, Benzene |
| Polyamide (PA) | Respirable dust, Methanal | 1,3-Butadiene, PAHs, Propenal, Benzene |
| Polypropylene (PP) | Respirable dust | 1,3-Butadiene, Propenal, Benzene |
| Polyethylene (PE) | Respirable dust | 1,3-Butadiene, Propenal, Benzene |
| Poly (vinyl chloride) (PVC) | Respirable dust, HCL | Benzene, Methanal, PAHs, Phosgene |
| Rubber (SBR-man made) | Respirable dust, 1,3-Butadiene | Styrene, PAHs, Propenal, Benzene |
| Polyester (PET) | Respirable dust | Benzene, Toluene, Ethylbenzene |
| Polystyrene (PS) | Respirable dust, Styrene | Benzene, Toluene, PAHs |
| Polyurethane (PU) | Respirable dust | Benzene, Toluene |
| Poly (PMMA) (methyl methacrylate) |
Respirable dust | MMA, Benzene, Ethylacrylate |
| Possible Effect of Emissions on Personnel | |
|---|---|
| Emission | Possible Effect on Personnel |
| Respirable dust | Occupational asthma |
| Cresol | Damage to liver/kidneys, dermatitis,cancer |
| NO/NO2 | Asphyxia |
| Phenol | Damage to liver/kidneys, digestive disorders |
| Phosgene | Pulmonary oedema |
| Benzene | Known carcinogen - Leukaemia |
| HCN | Respiratory failure |
| Chromium | Lung cancer, damage to liver and kidneys |
| Methanal | Severe skin and eye irritant |
| Nickel | Lung cancer, dermatitis |
| Styrene | Poisonous, irritant of respiratory tract |
| EXPOSURE LIMITS [OEL (8hr) mg/m3] | |
|---|---|
| Benzene | 9 |
| 1,3 Butadienne | 22 |
| Formaldehyde | 2.5 |
| Methylmethacrylate | 208 |
| Phenol | 20 |
| Creois | 22 |
| Toluene | 191 |
| Hydrogen Chloride | 2 |
| Phosgene | 0.08 |
| Methylamine | 13 |
| THF (Tetrahydrofuran) | 300 |

